The two-car crash happened on North Main Street shortly before 9 p.m. Saturday.
The driver of one of the cars, a 2013 Toyota Corolla, was driven by 47-year-old Margaret Spagnolo, from Whitman. She was taken to Brockton Hospital where she was pronounced dead.
The other vehicle involved in the crash, a 2002 Dodge Caravan, had a driver and passenger inside. Daniel Nowokunski, 51, and his wife Susan, 61, were taken to Good Samaritan Hospital and South Shore Hospital, respectively. There was no word on their conditions Sunday morning.
A cause of the crash has not yet been determined. State and local police are investigating.
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